Your Cars Oil and important info!

[PNYKLR2]

What does my oil actually do?

An engine oil's job is primarily to stop all the metal surfaces in your engine from grinding together and tearing themselves apart (and that's the last thing we'd want!). But it also has to dissipate the heat generated from this friction too. It also transfers heat away from the combustion cycle. Another function is that a good engine oil must be able to hold in suspension the nasty by-products of fuel combustion, such as silica (silicon oxide) and acids, whilst also cleaning the engine of such nasties. And it must do all of these things under tremendous heat and pressure without succumbing to fatigue or black death, the ultimate engine destroyer.

[PNYKLR2]

What the heck was Black Death?

Black death first appeared in the early 80's when a horrible sticky black substance was found to be the cause of many engine seizures in Europe. Many engines were affected but Ford and Vauxhall (GM) suffered the most. Faster roads, higher under-hood temperatures, tighter engineering tolerances and overworked engine oils turned out to be contributors to the problem. The oils just couldn't handle it and changed their chemical makeup under pressure into a sort of tar-like glue. This blocked all the oil channels in the engines, starved them of lubrication and caused them to seize. This could all happen in a matter of minutes. I don't recommend this but you can reproduce the effect with a frying pan, cooking oil and a blowtorch. The cooking oil will heat up far quicker than it's designed to and will turn to a sticky black tar in your pan. Either that or it will set fire to your kitchen, which is why I said "don't do this".
Anyway, burning kitchens aside, Black Death was the catalyst for the production of newer higher quality oils, many of them man-made rather than mineral-based.

Black death for the 21st century

There's a snappy new moniker for black death now, and it's called sludge. The cause is the same as black death and it seems to be regardless of maintenance or mileage. The chemical compounds in engine oils break down over time due to prolonged exposure to high temperatures and poor maintenance habits. When the oil oxidises, the additives separate from the oil and begin to chemically break down and solidify, leading to the baked-on oil deposits turning gelatinous, and that nasty compound is what is loving referred to nowadays as sludge. It's like black yoghurt. What doesn't help is that modern engines, due to packaging, have smaller sumps than in the "good old days" and so hold less oil. This means that the oil that is present in the engine can't hold as much crap (for want of a better word) and can lead to earlier chemical breakdown.
The most common factor in sludge buildup is mineral oils combined with a lack of maintenance by the car owner combined with harsh driving conditions. But this isn't true in all cases. For some reason, a 2005 Consumer Reports article discovered that some engines from Audi, Chrysler, Saab, Toyota, and Volkswagen appear prone to sludge almost no matter how often the oil is changed. VW and Audi have extended the warranties on the Passat engines to 8 years/unlimited milage and have been replacing the engines due to sludge buildup. Audi has the same problem with its transverse-mounted 1.8 Turbo engines. For their part, Toyota have the dubious honour of having the most complaints about sludge buildup in their engines - 3,400 at the last count.

[PNYKLR2]

What does sludge look like?
http://www.carbibles.com/images/sludge1.jpg

http://www.carbibles.com/images/sludge2.jpg

I was contacted by a BMW driver who's been having a particularly harsh time with sludge and has been discussing it on the Bimmerfest forums. He posted some images of his problem and other readers posted similarly-framed images of the same engine components in "normal" condition. Below are two of those photos. On the left is what the cam case should look like in a well maintained engine when photographed through the oil filler cap. On the right is what the same type of engine looks like when suffering sludge buildup.


In this example, the consensus was that the sludge buildup was caused by an overheating engine, oil that hadn't been changed for 20,000 miles of stop-go city driving, a lot of cold starts and a period of about 12 months in storage without an oil change. Most of this happened before the current owner got it.

Curing sludge

There's no hard and fast rules for curing an engine of sludge buildup. If it's really bad, flushing the engine might be the only cure, but that could also cause even more problems. If flushing the engine results in bits of sludge getting lodged where they can do more damage, you're actually worse off.
It's interesting to note that some race techs have reported sludge buildup in race engines as a result of aftermarket additives being used in conjunction with the regular oil. The chemical composition of the additives isn't as neutral as some companies would lead us to believe, and combined with particular types of oil and high-stress driving, they can cause oil breakdown and sludge to appear. The lesson from them appears to be "don't use additives".

[PNYKLR2]

When is sludge not sludge?

Easy. When it's an oil and water emulsion from a leaking or blown head gasket. If this happens, you get a whitish cream coloured sludge on the inside of the oil filler cap. The filler cap is typically cooler than the rest of the cam case and so the oil/water mix tends to condense there. So if you take the oil filler cap off and it looks like it's covered in vanilla yoghurt or mayonnaise, you've got a blown head gasket. A surefire way to confirm this is if your oil level is going up and your coolant level is going down. The coolant is getting through the breaks in the head gasket and mixing with the oil. When it gets to the sump it separates out and the oil floats on top. A slightly more accurate way to check for this condition is to use a combustion leak tester, or block tester. If you're in America, NAPA sell them for about $45 (part #BK 7001006). If you're in England, Sealey sell them for about £70 (model number VS0061). Combustion leak testers are basically a turkey baster filled with PH liquid, with a non-return valve at the bottom. To use one, run your engine for a few minutes until its warm (not hot) then turn it off. Use a protective glove (like an oven glove) and take the radiator or reservoir cap off. Plug the bottom of the combustion leak tester into the hole and squeeze the rubber bulb on top. It will suck air from the top of the coolant through the non-return valve and bubble it through the PH liquid. If the liquid changes colour (normally blue to yellow), it means there is combustion gas in the coolant, which means a head gasket leak.
There is one other possible cause for this yellow goop : a blocked scavenger hose. Most engines have a hose which comes off the cam cover and returns to the engine block somewhere via a vacuum line. This is the scavenger hose which scavenges oil vapour and gasses that build up in the cam cover. If it's blocked you can end up with a buildup of condensation inside the cam cover, which can manifest itself as the yellow goop inside the filler cap.

Mineral or synthetic?
Mineral oils are based on oil that comes from dear old Mother Earth which has been refined. Synthetic oils are entirely concocted by chemists wearing white lab coats in oil company laboratories. For more info, see the section on synthetics further down the page. The only other type is semi-synthetic, sometimes called premium, which is a blend of the two. It is safe to mix the different types, but it's wiser to switch completely to a new type rather than mixing.

[PNYKLR2]

A couple of words of warning:

If you've been driving around with mineral oil in your engine for years, don't switch to synthetic oil without preparation. Synthetic oils have been known to dislodge the baked-on deposits from mineral oils and leave them floating around your engine - not good. I learned this lesson the hard way! It's wise to use a flushing oil first.
If you do decide to change, only go up the scale. If you've been running around on synthetic, don't change down to a mineral-based oil - your engine might not be able to cope with the degradation in lubrication. Consequently, if you've been using mineral oil, try a semi or a full synthetic oil. By degradation, I'm speaking of the wear tolerances that an engine develops based on the oil that it's using. Thicker mineral oils mean thicker layers of oil coating the moving parts (by microns though). Switching to a thinner synthetic oil can cause piston rings to leak and in some very rare cases, piston slap or crank vibration.
Gaskets and seals! With the makeup of synthetic oils being different from mineral oils, mineral-oil-soaked gaskets and seals have been known to leak when exposed to synthetic oils. Perhaps not that common an occurrence, but worth bearing in mind nevertheless.
Synthetics
Despite their name, most synthetic derived motor oils (ie Mobil 1, Castrol Formula RS etc ) are actually derived from mineral oils - they are mostly Polyalphaolifins and these come from the purest part of the mineral oil refraction process, the gas. PAO oils will mix with normal mineral oils which means Joe public can add synthetic to his mineral, or mineral to his synthetic without his car engine seizing up. The most stable bases are polyol-ester (not polyester, you fool). When I say 'stable' I mean 'less likely to react adversely with other compounds.' Synthetic oil bases tend not to contain reactive carbon atoms for this reason. Reactive carbon has a tendency to combine with oxygen creating an acid. As you can imagine, in an oil, this would be A Bad Thing. So think of synthetic oils as custom-built oils. They're designed to do the job efficiently but without any of the excess baggage that can accompany mineral based oils.

Pure synthetics

Pure synthetic oils (polyalkyleneglycol) are the types used almost exclusively within the industrial sector in polyglycol gearbox oils for heavily loaded gearboxes. These are typically concocted by intelligent blokes in white lab coats. These chaps break apart the molecules that make up a variety of substances, like vegetable and animal oils, and then recombine the individual atoms that make up those molecules to build new, synthetic molecules. This process allows the chemists to actually "fine tune" the molecules as they build them. Clever stuff. But Polyglycols don't mix with normal mineral oils.

While we're on synthetic oils, I should mention Amsoil. I originally had them down as an additive. I was wrong. I've got to say I've had no experience of the product myself so I can't vent my spleen about it. However, there is a particularly good page with a ton of info about it here. I recommend you pop over and read this and see what you think.
I've been contacted by Amsoil themselves and asked to point out the following:
Amsoil do NOT produce or market oil additives and do not wish to be associated with oil additives. They are a formulator of synthetic lubricants for automotive and industrial applications and have been in business for 30+ years. They are not a half-hour infomercial or fly-by-night product, nor have they ever been involved in a legal suit regarding their product claims in that 30+ year span. Many Amsoil products are API certified, and ALL of our products meet and in most cases exceed the specifications of ILSAC, AGMA etc..... Their lubricants also exceed manufacturers specifications and Amsoil are on many manufacturers approval lists. They base their claims on ASTM certified tests and are very open to anyone, with nothing to hide.

It turns out that Amsoil actually have the stance that they recommend engine oil additives are NOT to be used with their products. This will become relevant later on this page, and in the additives section. They have a pretty good FAQ on the Amsoil website, which you can find here.

[PNYKLR2]

Flushing oils

These are special compound oils that are very, very thin. They almost have the consistency of tap water when cold as well as hot. Typically they are 0W/20 oils. Don't ever drive with these oils in the engine - it won't last. Their purpose is for cleaning out all the gunk which builds up inside an engine. Note that Mobil1 0W40 is okay, because the '40' denotes that it's actually thick enough at temperature to work. 0W20 just doesn't get that viscous! To use them, drain your engine of all it's oil, but leave the old oil filter in place. Next fill it up with flushing oil and run it at a fast idle for about 20 minutes. Finally, drain all this off (and marvel at the crap that comes out with it), replace the oil filter, refill with a good synthetic oil and voila! Clean engine.
Of course, like most things nowadays, there's a condition attached when using flushing oils. In an old engine you really don't want to remove all the deposits. Some of these deposits help seal rings, lifters and even some of the flanges between the heads, covers, pan and the block, where the gaskets are thin. I have heard of engines with over 280,000km that worked fine, but when flushed it failed in a month because the blow-by past the scraper ring(now really clean)contaminated the oil and screwed the rod bearings.

Using Diesel oil for flushing

A question came up some time ago about using diesel-rated oils to flush out petrol engines. The idea was that because of the higher detergent levels in diesel engine oil, it might be a good cleaner / flusher for a non-diesel engine. Well most of the diesel oil specification oils can be used in old petrol engines for cleaning, but you want to use a low specification oil to ensure that you do not over clean your engine and lose compression for example. Generally speaking, an SAE 15W/40 diesel engine oil for about 500 miles might do the trick.

A quick guide to the different grades of oil.

Fully Synthetic Characteristics
0W-30
0W-40
5W-40 Fuel economy savings
Enhances engine performance and power
Ensures engine is protected from wear and deposit build-up
Ensures good cold starting and quick circulation in freezing temperatures
Gets to moving parts of the engine quickly
Semi-synthetic Characteristics
5W-30
10W-40
15W-40 Better protection
Good protection within the first 10 minutes after starting out
Roughly three times better at reducing engine wear
Increased oil change intervals - don't need to change it quite so often
Mineral Characteristics
10W-40
15W-40 Basic protection for a variety of engines
Oil needs to be changed more often

[PNYKLR2]

So what should I buy?

Quality Counts! It doesn't matter what sort of fancy marketing goes into an engine oil, how many naked babes smear it all over their bodies, how bright and colourful the packaging is, it's what's written on the packaging which counts. Specifications and approvals are everything. There are two established testing bodies. The API (American Petroleum Institute), and the European counterpart, the ACEA (Association des Constructeurs Europeens d'Automobiles - which was the CCMC). You've probably never heard of either of them, but their stamp of approval will be seen on the side of every reputable can of engine oil.

The API

The API classifications are different for petrol and diesel engines:
For petrol, listings start with 'S' (meaning Service category, but you can also think of it as Spark-plug ignition), followed by another code to denote standard. 'SM' is the current top grade, which recently replaced 'SL' and 'SH'. 'SH' will be found on most expensive oils, and almost all the new synthetics. It's basically an upgraded 'SG' oil which has been tested more sternly.

For diesel oils, the first letter is 'C' (meaning Commercial category, but you can also think of it as Compression ignition). 'CH' is the highest grade at the moment, (technically CH-4 for heavy-duty) but 'CF' is the most popular and is well adequate for passenger vehicle applications.
Note about Castrol oils: Castrol have recently upgraded all their oils and for some reason, Castrol diesels now use the 'S' rating, thus completely negating my little aid-memoir above. So the older CC,CD,CE and CF ratings no longer exist, but have been replaced by an 'SH' grade diesel oil. This link is a service bulletin from Castrol themselves, explaining the situation.

The CCMC/ACEA

The ACEA standards are prefixed with a 'G' for petrol engines and a 'D' or 'PD' for diesel. Coupled with this are numerous approvals by car manufacturers which many oil containers sport with pride. ACEA replaced CCMC in 1996 primarily to allow for greater read-across in test programs (eg. for viscosity, viscosity modifiers and base oil). The CCMC specifications were G (1 to 5) for gasoline, D (1 to 5) or heavy duty diesel and PD1 and PD2 for passenger car diesel. ACEA though have a slightly different nomenclature they can be summarised as A for petrol, B for passenger car diesel and E for heavy duty diesel. The ACEA grades may also be followed by the year of issue which will be either '96, '98 (current) but coming soon is 2000.
Full ACEA specs are:

A1 Fuel Economy Petrol
A2 Standard performance level
A3 High performance and / or extended drain
B1 Fuel Economy diesel
B2 Standard performance level
B3 High performance and / or extended drain
B4 For direct injection passenger car diesel engines
E1 Non-turbo charged light duty diesel
E2 Standard performance level
E3 High performance extended drain
E4 Higher performance and longer extended drain
E5 (1999) High performance / long drain plus American/API performances. - This is ACEAs first attempt at a global spec.

[PNYKLR2]

Typically, these markings will be found in a statement similar to: Meets the requirements of API SH/CD along the label somewhere. Also, you ought to be able to see the API Service Symbol somewhere on the packaging:



If this is all confusing you, then rest assured that all top oils safely conform to the current standards. What you should treat with caution are the real cheapies and those with nothing but a maker's name on the pack. Anything below about £12 ($18) for 5 litres just isn't going to be worth it.

A Brief History of Time API ratings

Some people have asked about the old standards, and although they're not especially relevant, some rampant plagiarism from an API service bulletin means I can bring you all the API ratings right back from when the earth was cooling.

Petrol Engines Diesel Engines

Category Status Service Category Status Service
SM Current For all automotive engines presently in use. Introduced in the API service symbol in November 2004 CH-4 Current Introduced in 1998 for high-speed four-stroke engines. CH-4 oils are specifically designed for use with diesel fuels ranging in sulphur content up to 0.5% weight. Can be used in place of CD, CE, CF-4 and CG-4.
SL Current For all automotive engines presently in use. Introduced in the API service symbol in 1998 CG-4 Current Introduced in 1995 for high-speed four-stroke engines. CG-4 oils are specifically designed for use with diesel fuels ranging in sulphur content less than 0.5% weight. CG-4 oil needs to be used for engines meeting 1994 emission standards. Can be used in place of CD, CE and CF-4.
SJ Obsolete For all automotive engines presently in use. Introduced in the API service symbol in 1996 CF-4 Current Introduced in 1990 for high-speed four-stroke naturally aspirated and turbo engines. Can be used in place of CD and CE.
SH Obsolete For model year 1996 and older engines. CF-2 Current Introduced in 1994 for severe duty, two stroke motorcycle engines. Can be used in place of CD-II.
SG Obsolete For model year 1993 and older engines. CF Current Introduced in 1994 for off-road, indirect-injected and other diesel engines including those using fuel over0.5% weight sulphur. Can be used in place of CD.
SF Obsolete For model year 1988 and older engines. CE Obsolete Introduced in 1987 for high-speed four-stroke naturally aspirated and turbo engines. Can be used in place of CC and CD.
SE Obsolete For model year 1979 and older engines. CD-II Obsolete Introduced in 1987 for two-stroke motorcycle engines.
SD Obsolete For model year 1971 and older engines. CD Obsolete Introduced in 1955 for certain naturally aspirated and turbo engines.
SC Obsolete For model year 1967 and older engines. CC Obsolete Introduced in 1961 for all diesels.
SB Obsolete For older engines. Use this only when specifically recommended by the manufacturer. CB Obsolete Introduced in 1949 for moderate-duty engines.
SA Obsolete For much older engines with no performance requirement. Use this only when specifically recommended by the manufacturer. CA Obsolete Introduced in 1940 for light-duty engines.

Grade counts too!The API/ACEA ratings only refer to an oil's quality. For grade, you need to look at the SAE (Society of Automotive Engineers) ratings. These describe the oil's function and viscosity standard. Viscosity means the substance and clinging properties of the lubricant. When cold, oil can become like treacle so it is important that any lube is kept as thin as possible. It's cold performance is denoted by the letter 'W', meaning 'winter'. At the other end of the scale, a scorching hot oil can be as thin as water and about as useful too. So it needs to be as thick as possible when warm. Thin when cold but thick when warm? That's where MultiGrade oil comes in. For ages, good old 20W/50 was the oil to have. But as engines progressed and tolerances decreased, a lighter, thinner oil was required, especially when cold. Thus 15W/50, 15W/40 and even 15W/30 oils are now commonplace. Synthetics can go down as far as 5W which seemed unbeatable until Castrol came up with SLX - a 0W30 formulation! 'Free flowing' just doesn't describe it! It's predominantly a workshop oil retailing at around £10 ($15) a litre, but recommended for use in places like Canada in the winter. The latest offering to this 0W30 engineering miracle comes from AMSOIL.

So again: what should I buy? That all depends on your car, your pocket and how you intend to drive and service the car. All brands claim theirs offers the best protection available - until they launch a superior alternative. It's like washing powders - whiter than white until new Super-Nukem-Dazzo comes out. For most motorists and most cars, a quality mainline oil is the best. Ones which are known to be good at their job. Stuff like Castrol GTX. They're not too dear either. Don't believe the sales hype - they all perform to the same standards once they're out of the can and into your engine. Moving up a step, you could look at Duckhams QXR and Castrol Protection Plus and GTX3 Lightec. The latter two of these are designed specifically for engines with catalytic converters. They're also a good choice for GTi's and turbo'd engines. Go up a step again and you're looking at synthetic oils aimed squarely at the performance market. To get more money out of you, the manufacturers sell this stuff in smaller amounts which makes an oil change more expensive.

[PNYKLR2]

Engine Oil Shelf Life.

I couldn't decide whether to put this in the FAQ or the main page, so it's in both, because I get asked this question a lot. Typically, the question is along the lines of "GenericAutoSuperStore are having a sale on WickedlySlippy Brand synthetic oil. If I buy it now, how long can I keep if before I use it?"
In general, liquid lubricants (ie. oils, not greases) will remain intact for a number of years. The main factor affecting the life of the oil is the storage condition for the products. Exposure to extreme temperature changes, and moisture will reduce the shelf life of the lubricants. ie. don't leave in the sun with the lid off. Best to keep them sealed and unopened.

Technically, engine oils have shelf lives of four to five years. However, as years pass, unused engine oils can become obsolete and fail to meet the technical requirements of current engines. The specs get updated regularly based on new scientific testing procedures and engine requirements. But this is only really a concern if you've bought a brand new car but have engine oil you bought for the previous car. An oil that is a number of years old might not be formulated to meet the requirements set for your newer engine.

If your unopened containers of engine oil are more than three years old, read the labels to make sure they meet the latest industry standards. If they do meet the current standards, you might want to take the extra precaution of obtaining oil analysis before using them. An oil analysis will check for key properties of the oil and ensure that it still meets the original manufacturing specs. Of course the cost of getting an analysis done on old oil is probably going to outweigh going and buying fresh stuff. So it's a double-edged sword.
As a general rule, the simpler the oil formulation, the longer the shelf life. The following is a guideline under protected conditions:

Product Shelf Life

Base Oils, Process Oils 3 years
Hydraulic Oils, Compressor Oils, General Purpose Lubricating Oils 2 years
Engine Oils and Transmission Oils 3 years
Industrial and Automotive Gear Oils 2 years
Metal Working and Cutting Oils 1 year

The following are signs of storage instability in a lubricant:

Settling out of the additives as a gel or sticky liquid
Floc or haze
Precipitates/solid material
Colour change or haziness
Water contamination in a lubricant can be detected by a "milky" appearance of the product.

[PNYKLR2]

So how often should I change my oil?

You can never change your engine oil too frequently. The more you do it, the longer the engine will last. The whole debate about exactly when you change your oil is somewhat of a grey area. Manufacturers tell you every 10,000 miles or so. Your mate with a classic car tells you every 3,000 miles. Ole' Bob with the bad breath who drives a truck tells you he's never once changed the oil in his car. Fact is, large quantities of water are produced by the normal combustion process and, depending on engine wear, some of it gets into the crank case. If you have a good crank case breathing system it gets removed from there PDQ, but even so, in cold weather a lot of condensation will take place. This is bad enough in itself, since water is not noted for its lubrication qualities in an engine, but even worse, that water dissolves any nitrates formed during the combustion process. If my memory of chemistry serves me right, that leaves you with a mixture of Nitric (HNO3) and Nitrous (HNO2) acid circulating round your engine! So not only do you suffer a high rate of wear at start-up and when the engine is cold, you suffer a high rate of subsequent corrosion during normal running or even when stationary.
The point I'm trying to make is that the optimum time for changing oil ought to be related to a number of factors, of which distance travelled is probably one of the least important in most cases. Here is my selection in rough order of importance:

Number of cold starts (more condensation in a cold engine)
Ambient temperature (how long before warm enough to stop serious condensation)
Effectiveness of crank case scavenging (more of that anon)
State of wear of the engine (piston blow-by multiplies the problem)
Accuracy of carburation during warm-up period (extra gook produced)
Distance travelled (well, lets get that one out of the way)
If you were clever (or ****) enough, you could probably come up with a really clever formula incorporating all those factors. However, I would give 1, 2, and 3 equal top weighting. Items 1 to 3 have to be taken together since a given number of "cold" starts in the Dakar in summer is not the same as an equal number conducted in Fargo in January. The effect in either case will be modified by how much gas gets past the pistons. What we are really after is the severity and duration of the initial condensation period. All other things being equal, that will give you how much condensate will be produced and I would suggest that more than anything else determines when the oil should be dumped.

[PNYKLR2]

If you would like source files and or sites for this information please send me a PM.

[Phoenix 5.7]

very good info. i might suggest a link in the first post to each section(different post).

[NoChrome]

Im currious about the PAO. I work with this stuff ALOT, do you think you could go more in depth on it?

[PNYKLR2]

sure no problem I'll have some info up tomorrow, its 4:30am lol and I'm not capable of thinking right now

[PNYKLR2]

PAO's or synthetic polyalphaolefin oils-
(One process for making synthetic base oils is to start with a chemical called an olefin, and make new molecules by attaching them to each other in long chains, hence "poly." The primary advantage of Poly-Alpha-Olefin "PAO" base oil is that all the molecules in the base oil are pretty much identical, so it's easy to get the base oil to behave exactly as you like. PAOs are called Group IV base oils.)


-Most "synthetic oils" today aren't even synthetic. Most are produced from the Group III oil base. So most likely that "synthetic oil" your using is just a Group III oil that has been highly distilled and refined. Don't get me wrong its still a great oil. Group III oil's have a very high VI levels, rating over 120.

To the best of my knowledge, Delvac-1, AMSOil, Redline, and Motul 5100 are the only oils made from pure traditional synthetics.


-Synthetic oils were originally designed for the purpose of having a very pure base oil with excellent properties. By starting from scratch and building up your oil molecules from little pieces, you can pretty much guarantee that every molecule in the oil is just like every other molecule, and therefore the properties are exactly what you designed in, not compromised by impurities from dead cockroach shells or whatever. Synthetics were thus originally a reaction to the relatively poor refining processes available from about 1930 to about 1990. The original synthetics were designed for the Army Air Force in WW II. They simply could not make their high- performance turbo-charged radial engines stay alive on the available motor oils of the time.

-Finally, there are new chemicals emerging which are made from liquefied natural gas called GTL (gas to liquid) base oils. These will be called Group III+, and many people think they will become an important part of the oils you buy by 2010. These GTL base oils have natural VIs of 140 or more, meaning for most applications they won't require any VII package at all. Natural gas is primarily made up of only one type of molecule, so the refining is already done for you. Most oil wells throw off a lot of natural gas. In many cases, it's more expensive to transport this gas to a large city than the gas is worth, so it's just burned off. For example, Iran burns off enough natural gas each day to power their entire country, electricity, cars, ships, airplanes, the whole thing. So the next time you hear Iran's nuclear reactors are purely for peaceful production of energy, you can wonder like the rest of us why a country that burns off more than their entire energy needs must spend tens of billions of dollars developing alternative energy sources. Well, anyway, natural gas is a chemical looking for a use. All you have to do is chemically attach these molecules to each other to turn them into quite pure oil stocks.

"Semi-synthetics" are oils which are a blend of petroleum oil and no more than 30% synthetic oil. If the manufacturer adds no more than 30% synthetic oil and does not change the additive package, they do not have to recertify the oil. These days, since everyone has agreed that Group III base oils are "synthetic," I'm not sure "semi-synthetic" means anything at all. The manufacturers love this stuff: it costs about 15% more to make the oil, and they get to charge about double. I don't recommend semi-synthetics. Save your money and take your kids to McDonalds.




I hope this answers anything you have with PAO's